约翰尼·维加斯
Johnny Vegas
饰：Himself
Emma Boughton
饰：Herself
加里·巴洛
Gary Barlow
饰：自己
大卫·哈塞尔霍夫
David Hasselhoff
饰：自己
詹姆斯·柯登
James Kimberley Corden
饰：自己
金伯利·沃什
Kimberley Walsh
饰：自己
谢丽尔
Cheryl Tweedy
饰：自己
温国兴
Gok Wan
饰：自己
杰米·奥利弗
Jamie Oliver
饰：自己
Cheryl
Cheryl
饰：嘉宾
凯莉·米洛
Kylie Minogue
饰：Herself - Host
马修·豪勒
Mathew Horne
饰：Himself - Host
Adele
Adele
饰：Herself - Presenter
Little Boots
饰：Herself
Joe Calzaghe
Joe Calzaghe
饰：Himself - Presenter
阿比盖尔·克兰西
Abigail Clancy
饰：Herself
娜丁·科伊尔
Nadine Coyle
饰：Herself - Performer (as Girls Aloud)
艾莉莎·迪克森
Alesha Dixon
饰：Herself
达菲
Duffy
饰：Herself - Performer
Elbow
饰：Themselves - Winner, Best British Group Award
尼克·弗罗斯特
Nick Frost
饰：Himself - Presenter
皮格茜· 盖尔多夫
Pixie Geldof
饰：Herself
莎拉·哈丁
Sarah Harding
饰：Herself - Performer (as Girls Aloud)
娜塔莉·安博莉亚
Natalie Imbruglia
饰：Herself - Presenter
凯瑟琳·詹金斯
Katherine Jenkins
饰：Herself
Jules De Martino
饰：Himself
皮尔斯·摩根
Piers Morgan
饰：Himself
杰森·奥兰奇
Jason Orange
饰：Himself - Performer (as Take That)
西蒙·佩吉
Simon Pegg
饰：Himself - Presenter
妮科拉·罗伯茨
Nicola Roberts
饰：Herself - Performer (as Girls Aloud)
Taylor Swift
Taylor Swift
饰：Herself
U2乐队
U2
饰：Themselves - Performer
保罗·韦勒
Paul Weller
饰：Himself - Winner, Best British Male Solo Artist Award
霍莉·威洛比
Holly Willoughby
饰：Herself
菲妮·科顿
Fearne Cotton
饰：Herself - Backstage Presenter
亚历山德拉·伯克
Alexandra Burke
饰：Herself
艾伦·卡尔
Alan Carr
饰：Himself - Presenter
艾里珊·钟
Alexa Chung
饰：Herself
杰米·卡拉姆
Jamie Cullum
饰：Himself - Presenter
霍华德·唐纳德
Howard Donald
饰：Himself - Performer (as Take That)
塔玛拉·埃克尔斯通
Tamara Ecclestone
饰：Herself
艾丝黛儿
Estelle
饰：Herself - Performer
布兰登·弗劳尔斯
Brandon Flowers
饰：Himself - Performer
Lady Gaga
Stefani Joanne Angelina Germanotta
饰：Herself - Performer
加尔文·哈里斯
Calvin Harris
饰：Himself
阿曼达·霍顿
Amanda Holden
饰：Herself
阿历克斯·詹姆斯
Alex James
饰：Himself - Presenter
汤姆·琼斯
Tom Jones
饰：Himself - Presenter
Del Mak
饰：Himself - Principle Dancer
Liz McClarnon
饰：Herself
马克·欧文
Mark Owen
饰：Himself - Performer (as Take That)
Katy Perry
Katy Perry
饰：Herself - Winner, Best International Female Solo Artist Award
莱昂纳尔·里奇
Lionel Richie
饰：Himself - Presenter
Take That
饰：Themselves
K.T.邓斯托尔
K.T. Tunstall
饰：Herself
弗洛伦斯·威尔奇
Florence Welch
饰：Herself
Katie White
饰：Herself
Eglantina Zingg
饰：Herself - Host for t5m.com